192c Redox Thermodynamics of Ceria and Ceria Mixed Oxides

Raymond J. Gorte, Department of Chemical and Biomolecular Engineering, University of Pennsylvania, Room 311A Towne Building, 220 South 33rd Street, Philadelphia, PA 19104

Ceria plays a critical role in three-way automotive catalysis because of its oxygen-storage capacitance. More recently, these same redox properties have been shown to make ceria a good promoter for steam-reforming, water-gas-shift, and hydrocarbon-oxidation catalysis. Scientifically, ceria is also interesting because its redox properties change when it is mixed with other oxides or prepared in a nanocrystalline form. In the automotive application for example, it is necessary to mix ceria with zirconia in order to have a material with sufficient thermal stability. This talk will outline some of the key applications for ceria in catalysis. The fundamental thermodynamic properties that allow these applications will then be discussed.