112e Reactor Simulation for Industrial Process Using Sulfite Oxidation in Water

Ruth E. Kuilan, Chemical Engineering, University of Puerto Rico Mayaguez Campus, 320 Tous Soto St., Urb. Baldrich, San Juan, PR 00918

Abstract

Air Products and Chemicals, Inc. would like to improve a current process that uses a reactive gas to form a gas product in a Continuous Stirred Tank Reactor (CSTR). It has been determined that oxygen (O2) and nitrogen (N2) are two gases that can be used to simulate this reaction. Therefore, the aim of this project is to investigate the rate at which O2 is absorbed when it reacts with a sodium sulfite (Na2SO3) solution while in the presence of cobalt sulfate (CoSO4) as a catalyst. Under the conditions chosen, the reaction of oxygen can be considered sufficiently fast that the O2 concentration in the reactor is practically zero. Therefore the O2 uptake rate is affected primarily by mixing and is a direct measure of the O2 mass transfer rate. The following equation shows the oxidation reaction that will be completed:

Na2SO3 + 1/2 O2 → Na2SO4

This project will be realized with the intent of simulating a modified industrial process of one of the company's various products. By modifying this industrial process it is expected to obtain a better yield of the product with the same amount of raw material. This will result in the optimization of an existing process, which will eventually lead to economical savings.